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phase a is pure species 2 and phase is pure species 1 Thus lines ACG and B D H of Fig 1416 become in Fig 1420(a) vertical lines at xl = 0 and xl = 1 In region I, vapor phases with compositions represented by line BE are in equilibrium with pure liquid 1 Similarly, in region 11, vapor phases whose compositions lie along line A E are in equilibrium with pure liquid 2 Liquidlliquid equilibrium exists in region 111, where the two phases are pure liquid 1 and pure liquid 2 If one cools a vapor mixture starting at point m , the constant-composition path is represented by the vertical line shown in the figure At the dewpoint, where this line crosses line B E , pure liquid 1 begins to condense Further reduction in temperature toward T* causes continued condensation of pure liquid 1; the vapor-phase composition progresses along line BE until it reaches point E Here, the remaining vapor condenses at temperature T * , producing two liquid phases, one of pure species 1 and the other of pure species 2 A similar process, carried out to the left of point E , is the same, except that pure liquid 2 condenses initially The constant-temperature phase diagram for an immiscible system is represented by Fig 1420(b) Numerical calculations for immiscible systems are particularly simple, because of the following equalities:

x; = 1

y; = 1

W H AT I T TA K E S T O B E # 1

Js)(54 1014 s 1)(1 kJ/1000 J)(6022 1023/mol)

The three-phase-equilibrium pressure P* as given by Eq (1475) is therefore:

from which, by Eq (1476),

.

For region I where vapor is in equilibrium with pure liquid 1, Eq (105) becomes:

Similarly, for region I1 where vapor is in equilibrium with pure liquid 2,

= 22 10 kJ/mol Give yourself 1 point for each of these answers If you did the problem as a one-step problem, give yourself 2 points if you got the final answer correct, or 1 point if you left out any of the conversions The total for this question is 6 points, minus 1 point if any answer does not have the correct number of significant figures

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Prepare a table of ternperaturelcomposition data for the benzene(l)/water(2) system at a pressure of 10133 kPa (1 atm) from the vapor-pressure data in the accompanying table

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